{Reference Type}: Journal Article
{Title}: Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of β-Ketocarbonyl Compounds with Allylic Alcohols.
{Author}: Zhou H;Zhang L;Xu C;Luo S;
{Journal}: Angew Chem Int Ed Engl
{Volume}: 54
{Issue}: 43
{Year}: Oct 2015 19
{Factor}: 16.823
{DOI}: 10.1002/anie.201505946
{Abstract}: An efficient dual catalytic system composed of a chiral primary amine and a palladium complex was developed to promote the direct asymmetric allylic alkylation (AAA) of β-ketocarbonyl compounds. In particular, the synergistic dual catalytic system enabled the AAA reaction of challenging acyclic aliphatic ketones, such as β-ketocarbonyl compounds and 1,3-diketones.