%0 Journal Article
%T Influence of Diluent on Extraction Parameters of Systems for Separation Am(III) and Ln(III) Based on 1,10-Phenanthroline-2,9-Diamide.
%A Gerasimov MA
%A Matveev PI
%A Evsiunina MV
%A Khult EK
%A Kalle P
%A Petrov VS
%A Lemport PS
%A Petrov VG
%A Kostikova GV
%A Ustynyuk YA
%A Nenajdenko VG
%J Molecules
%V 29
%N 15
%D 2024 Jul 28
%M 39124953
%F 4.927
%R 10.3390/molecules29153548
%X A systematic study of extraction systems for the separation of f-elements using the tetradentate N,O-donor diamide of 1,10-phenanthroline-2,9-dicarboxylic acid (L) in various molecular and ionic solvents was performed. It was demonstrated that the nature of a diluent has a significant impact on solvent extraction of Am(III) and Ln(III) and the stoichiometry of formed complexes with f-elements. The mechanism of complexation and forms of complexes in different diluents were investigated by radiometric methods, UV-vis titration, and XRD.