%0 Journal Article %T A monoclinic polymorph of chloro-thia-zide. %A Brydson RKH %A Kennedy AR %J Acta Crystallogr E Crystallogr Commun %V 80 %N 0 %D 2024 Jun 1 %M 38974168 暂无%R 10.1107/S2056989024006078 %X A new polymorph of the diuretic chloro-thia-zide, 6-chloro-1,1-dioxo-2H-1,2,4-benzo-thia-zine-7-sulfonamide, C7H6ClN3O4S2, is described. Crystallized from basic aqueous solution, this monoclinic polymorph is found to be less thermodynamically favoured than the known triclinic polymorph and to feature only N-H⋯O type inter-molecular hydrogen bonds as opposed to the N-H⋯O and N-H⋯N type hydrogen bonds found in the P1 form.