%0 Journal Article %T Experimental optical properties explained by density functional theory of the natural red algae for dye-sensitized solar cells application. %A Anoua R %A Touhtouh S %A El Jouad M %A Hajjaji A %A Bakasse M %A Sahraoui B %A Płóciennik P %A Zawadzka A %J Environ Sci Pollut Res Int %V 31 %N 23 %D 2024 May 30 %M 38689042 %F 5.19 %R 10.1007/s11356-024-33461-0 %X The present study investigates the usage of a novel natural dye derived from red algae of Morocco in dye-sensitized solar cells (DSSCs) for the first time. The main pigments responsible for sensitizing the semiconductor TiO2 coatings in the red algae were identified as phycoerythrin, carotenoid, and chlorophyll. The efficiency of a DSSC made from red algae was compared to that of a solar cell made from chlorophyll alone. The photovoltaic performance of the DSSC was evaluated through photocurrent density to photovoltage (J-V) characteristic analysis, and the efficiency was found to be 0.93%. To gain insights into its behavior, the absorbance and photoluminescence in a broad range were studied. Both absorbance and photoluminescence exhibited a broad-spectrum range. Additionally, electronic properties, such as HOMO, LUMO, energy gap, and chemical reactivity parameters, were studied using density functional theory (DFT) calculations.