%0 Journal Article
%T Neem biomass derived carbon quantum dots synthesized via one step ultrasonification method for ecofriendly methylene blue dye removal.
%A Waseem Basha Z
%A Muniraj S
%A Senthil Kumar A
%J Sci Rep
%V 14
%N 1
%D 2024 Apr 27
%M 38678104
%F 4.996
%R 10.1038/s41598-024-59483-9
%X This article presents a one-step ultrasonication technique for generating biomass carbon dots (BCDs) from neem bark (Azadirachta indica) powder. The BCDs were characterized using modern techniques such as UV-Vis, FTIR, Raman, XRD, HRTEM, FESEM, EDAX, and Zeta potential analyses. Unlike traditional nanocomposite bed systems, this study utilized BCDs as a liquid-phase adsorbent for the regenerative adsorption of the environmentally harmful dye, methylene blue (MB), through an in-situ precipitation reaction. This involved the formation of BCDs-MB adduct via an electrostatic mechanism. The adsorption capacity and percentage of removal were remarkable at 605 mg g-1 and 64.7% respectively, exceeding various solid-based adsorption methods in the literature. The Langmuir isotherm and pseudo-second-order kinetics model provided an excellent fit for this system. The calculated thermodynamic parameter, Gibbs free energy change (ΔG) was negative, indicating a spontaneous, exothermic, and physisorption-based mechanism. The regenerative capacity of our system was further demonstrated by successfully extracting and recovering the MB dye (64%) using ethyl alcohol as the solvent. This method provides an efficient means of recovering valuable cationic organic dye compounds from contaminated environments.