%0 Journal Article
%T Oxygen quenching of structurally characterized [5,10,15,20-tetrakis(4-fluoro-2,6-dimethylphenyl)porphyrinato]platinum(II).
%A Dash ZS
%A Huang RQ
%A Kimber AN
%A Olubajo OT
%A Polk M
%A Rancu OP
%A Zhang LL
%A Fu J
%A Nagelj N
%A Reynolds KG
%A Zheng SL
%A Dogutan DK
%J Acta Crystallogr C Struct Chem
%V 80
%N 0
%D 2024 Mar 1
%M 38407217
%F 1.184
%R 10.1107/S2053229624001621
%X The compound [5,10,15,20-tetrakis(4-fluoro-2,6-dimethylphenyl)porphyrinato]platinum(II), [Pt(C52H40F4N4)] or Pt(II)TFP, has been synthesized and structurally characterized by single-crystal X-ray crystallography. The Pt porphyrin exhibits a long-lived phosphorescent excited state (τ0 = 66 µs), which has been characterized by transient absorption and emission spectroscopy. The phosphorescence is extremely sensitive to oxygen, as reflected by a quenching rate constant of 5.0 × 108 M-1 s-1, and as measured by Stern-Volmer quenching analysis.