%0 Journal Article %T Synthesis of aliphatic nitriles from cyclobutanone oxime mediated by sulfuryl fluoride (SO2F2). %A Chen XL %A Qin HL %J Beilstein J Org Chem %V 19 %N 0 %D 2023 %M 37377774 %F 2.544 %R 10.3762/bjoc.19.68 %X A SO2F2-mediated ring-opening cross-coupling of cyclobutanone oxime derivatives with alkenes was developed for the construction of a range of δ-olefin-containing aliphatic nitriles with (E)-configuration selectivity. This new method features wide substrate scope, mild conditions, and direct N-O activation.