%0 Journal Article
%T Conjugated Copper-Catecholate Framework Electrodes for Efficient Energy Storage.
%A Liu J
%A Zhou Y
%A Xie Z
%A Li Y
%A Liu Y
%A Sun J
%A Ma Y
%A Terasaki O
%A Chen L
%J Angew Chem Int Ed Engl
%V 59
%N 3
%D Jan 2020 13
%M 31674098
%F 16.823
%R 10.1002/anie.201912642
%X A conjugated copper(II) catecholate based metal-organic framework (namely Cu-DBC) was prepared using a D2 -symmetric redox-active ligand in a copper bis(dihydroxy) coordination geometry. The π-d conjugated framework exhibits typical semiconducting behavior with a high electrical conductivity of ca. 1.0 S m-1 at room temperature. Benefiting from the good electrical conductivity and the excellent redox reversibility of both ligand and copper centers, Cu-DBC electrode features superior capacitor performances with gravimetric capacitance up to 479 F g-1 at a discharge rate of 0.2 A g-1 . Moreover, the symmetric solid-state supercapacitor of Cu-DBC exhibits high areal (879 mF cm-2 ) and volumetric (22 F cm-3 ) capacitances, as well as good rate capability. These metrics are superior to most reported MOF-based supercapacitors, demonstrating promising applications in energy-storage devices.