Abstract:
Circularly polarized luminescence (CPL) materials have been widely used in the fields of bioimaging, optoelectronic devices, and optical communications. The supramolecular interaction, involving harnessing non-covalent interactions between host and guest molecules to control their arrangements and assemblies, represents an advanced approach for facilitating the development of CPL materials and finely constructing and tuning the desired CPL properties. Cyclodextrins (CDs) are cyclic natural polysaccharides, which have also been ubiquitous in various fields such as molecular recognition, drug encapsulation, and catalyst separation. By adjusting the interactions between CDs and guest molecules precisely, composite materials with CPL properties can be facilely generated. This review aims to outline the design strategies and performance of CD-based CPL materials comprehensively and provides a detailed illustration of the interactions between host and guest molecules.
摘要:
圆偏振发光(CPL)材料在生物成像领域得到了广泛的应用,光电器件,和光通信。超分子相互作用,涉及利用主体和客体分子之间的非共价相互作用来控制它们的排列和组装,代表了一种先进的方法,可以促进CPL材料的开发,并精细地构建和调整所需的CPL性能。环糊精(CD)是环状天然多糖,它们在分子识别等各个领域也普遍存在,药物封装,和催化剂分离。通过精确调整CD和客体分子之间的相互作用,具有CPL性能的复合材料可以很容易地产生。本文旨在全面概述基于CD的CPL材料的设计策略和性能,并详细说明主体和客体分子之间的相互作用。