Abstract：
The realm of titanium coordination polymer research is still in its nascent stages and presents a formidable challenge in the field of coordination chemistry. In recent decades, the focus has predominantly been on manipulating titanium reactions in solution, resulting in the synthesis of ≈60 targeted compounds. Despite the limited number of documented instances, these materials showcase a diverse array of structures, encompassing 1D chains, 2D layers, and 3D frameworks. This suggests potential for fine-tuning coordination modes and structural features in future investigations. Moreover, titanium coordination polymers not only exhibit photo-active and photo-responsive properties but also hold promise for various other significant applications. This article offers an exhaustive review tracing the evolution of titanium coordination polymer development while providing an update on recent advancements. The review encompasses a synopsis of reported synthetic strategies, methodologies, structural diversity, and associated applications. Additionally, it delves into critical issues that necessitate attention for future progressions and proposes potential avenues to effectively propel this research field forward at an accelerated pace.
摘要：
钛配位聚合物的研究领域仍处于起步阶段，在配位化学领域提出了严峻的挑战。近几十年来,重点主要是操纵溶液中的钛反应，导致合成约60种目标化合物。尽管记录的实例数量有限，这些材料展示了各种各样的结构，包括1D链，2D图层,和3D框架。这表明在未来的研究中可能会微调协调模式和结构特征。此外，钛配位聚合物不仅具有光活性和光响应性能，而且还具有各种其他重要应用的前景。本文提供了详尽的综述，追踪了钛配位聚合物发展的演变，同时提供了最新进展的最新信息。这篇综述概述了报告的综合策略，方法论，结构多样性，和相关的应用程序。此外,它深入研究了需要关注未来进展的关键问题，并提出了有效推动这一研究领域加速发展的潜在途径。
