Abstract:
The aqueous zinc ion battery emerges as the promising candidate applied in large-scale energy storage system. However, Zn anode suffers from the issues including Zn dendrite, Hydrogen evolution reaction and corrosion. These challenges are primarily derived from the instability of anode/electrolyte interface, which is associated with the interfacial charge density distribution. In this context, the recent advancements concentrating on the strategies and mechanism to regulate charge density at the Zn anode/electrolyte interface are summarized. Different characterization techniques for charge density distribution have been analysed, which can be applied to assess the interfacial zinc ion transport. Additionally, the charge density regulations at the Zn anode/electrolyte interface are discussed, elucidating their roles in modulating electrostatic interactions, electric field, structure of solvated zinc ion and electric double layer, respectively. Finally, the perspectives and challenges on the further research are provided to establish the stable anode/electrolyte interface by focusing on charge density modifications, which is expected to facilitate the development of aqueous zinc ion battery.
摘要:
水性锌离子电池成为大规模储能系统中应用的有希望的候选者。然而,Zn阳极遭受的问题包括Zn枝晶,析氢反应和腐蚀。这些挑战主要来自阳极/电解质界面的不稳定性,这与界面电荷密度分布有关。在这种情况下,总结了有关调节Zn阳极/电解质界面电荷密度的策略和机理的最新进展。已经分析了不同的电荷密度分布表征技术,可用于评估界面锌离子传输。此外,讨论了Zn阳极/电解质界面的电荷密度规律,阐明它们在调节静电相互作用中的作用,电场,溶剂化锌离子和双电层的结构,分别。最后,对进一步研究的观点和挑战提供了建立稳定的阳极/电解质界面,重点是电荷密度的修改,有望促进水性锌离子电池的发展。