Abstract：
C─H Functionalization of heteroarenes stands as a potent instrument in organic synthesis, and with the incorporation of visible light, it emerged as a transformative game-changer. In this domain, electron donor-acceptor (EDA) complex, formed through the pairing of an electron-rich substrate with an electron-accepting molecule, has garnered substantial consideration in recent years due to the related avoidance of the requirement of photocatalyst as well as oxidant. EDA complexes can undergo photoactivation under mild conditions and exhibit high functional group tolerance, making them potentially suitable for the functionalization of biologically relevant heteroarenes. This review article provides an overview of recent advancements in the field of C─H functionalization of heteroarenes via EDA complex photoactivation with literature coverage up to April, 2024.
摘要：
C─H杂芳烃的官能化是有机合成中的有效工具，随着可见光的结合，它成为一个变革性的游戏规则改变者。在这个领域，电子供体-受体（EDA）复合物，通过富电子底物与电子接受分子的配对形成，近年来，由于避免了对光催化剂和氧化剂的需求，因此引起了广泛的考虑。EDA复合物可以在温和条件下进行光活化，并表现出高的官能团耐受性，使它们潜在地适合于生物相关的异芳烃的功能化。这篇综述文章概述了通过EDA络合物光活化对杂芳烃进行C-H官能化领域的最新进展，文献报道截至4月，2024.
