PDF(Pubmed)
Abstract：
For many years, metal-flavonoid complexes have been widely studied as a part of drug discovery programs, but in the last decade their importance in materials science has increased significantly. A deeper understanding of the role of metal ions and flavonoids in constructing simple complexes and more advanced hybrid networks will facilitate the assembly of materials with tailored architecture and functionality. In this Review, we highlight the most essential data on metal-flavonoid systems, presenting a promising alternative in the design of hybrid inorganic-organic materials. We focus mainly on systems containing CuII/I and FeIII/II ions, which are necessary in natural and industrial catalysis. We discuss two kinds of interactions that typically ensure the formation of metal-flavonoid systems, namely coordination and redox reactions. Our intention is to cover the fundamentals of metal-flavonoid systems to show how this knowledge has been already transferred from small molecules to complex materials.
摘要：
多年来,作为药物发现计划的一部分，金属-类黄酮复合物已被广泛研究，但是在过去的十年中，它们在材料科学中的重要性显着增加。对金属离子和类黄酮在构建简单复合物和更先进的混合网络中的作用的更深入理解将促进具有定制结构和功能的材料的组装。在这篇评论中,我们强调了金属-类黄酮系统的最基本数据，在混合无机-有机材料的设计中提出了有希望的替代方案。我们主要关注含有CuII/I和FeIII/II离子的系统，这在天然和工业催化中是必需的。我们讨论了两种通常确保金属-类黄酮系统形成的相互作用，即配位和氧化还原反应。我们的目的是涵盖金属类黄酮系统的基本原理，以展示这些知识如何从小分子转移到复杂的材料。
