关键词: Citrus latifolia FD factor GC/MS-O RFA values aroma extract dilution analysis sensorial evaluation

Mesh : Citrus / chemistry Odorants / analysis Taste Flavoring Agents / chemistry Humans Gas Chromatography-Mass Spectrometry Fruit / chemistry Volatile Organic Compounds / chemistry Smell Plant Oils / chemistry Female Limonene / chemistry analysis Male Adult

来  源:   DOI:10.1021/acs.jafc.4c02059

Abstract:
A modified aroma extract dilution approach (AEDA), followed by the determination of flavor dilution (FD) factors, a quantitative analysis and calculation of the relative flavor activity (RFA) and odor activity values (OAVs) as well as recombination experiments were conducted to evaluate the odor- and taste-relevant components of cold-pressed Citrus latifolia peel oil. A 2-fold concentration by distillation and reanalysis, compared with the original oil, revealed relevant components. Partition of the odor-active substances into four reconstitution groups according to their respective FD factors, followed by a recombination, allowed for a better understanding of the contribution of each FD-factor group to the overall aroma. Especially α-pinene, limonene, γ-terpinene, and 7-methoxycoumarin contribute significantly to the distinct aroma profile of C. latifolia. Heptadecanal (CAS 629-90-3) was described for the first time as an odor-active substance in an enriched C. latifolia peel oil. Campherenyl acetate (CAS 18530-07-9) was identified in nature for the first time and described with a herbal, minty and citrus-like odor. The odor profile of the final recombinant mixture, containing 36 components, was similar to cold-pressed C. latifolia peel oil for most descriptors, whereas the taste profile was described as more aldehydic and citral-like.
摘要:
改进的香气提取物稀释方法(AEDA),其次是确定风味稀释(FD)因素,进行了相对风味活性(RFA)和气味活性值(OAV)的定量分析和计算以及重组实验,以评估冷榨柑橘皮油的气味和味道相关成分。蒸馏和再分析的2倍浓度,与原始油相比,揭示了相关成分。根据其各自的FD因子将气味活性物质分为四个重建组,然后是重组,可以更好地了解每个FD因子组对整体香气的贡献。尤其是α-pine烯,柠檬烯,γ-萜品烯,和7-甲氧基香豆素对C.latifolia的独特香气谱有显着贡献。七烷醛(CAS629-90-3)首次被描述为富含C.latifolia果皮油中的气味活性物质。乙酸樟脑酯(CAS18530-07-9)首次在自然界中被鉴定,并用草药描述,薄荷味和柑橘味。最终重组混合物的气味特征,包含36种成分,对于大多数描述符,类似于冷压C.latifolia果皮油,而味道特征被描述为更多的醛和柠檬醛样。
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