关键词: electrochemical property epoxy ionic conductivity mechanical strength solid polymer electrolyte thermal stability

来  源:   DOI:10.3389/fchem.2024.1330655   PDF(Pubmed)

Abstract:
The potential applications of epoxy-based solid polymer electrolytes are continually expanding because of their versatile characteristics. These characteristics include mechanical rigidity, nonvolatility, nonflammability, and electrochemical stability. However, it is worth noting that pure epoxy-based solid polymer electrolytes inherently exhibit lower ion transport capabilities when compared to traditional liquid electrolytes. Striking a balance between high mechanical integrity and superior ionic conductivity at room temperature poses a significant challenge. In light of this challenge, this review is dedicated to elucidating the fundamental concepts of epoxy-based solid polymer electrolytes. It will explore various preparation techniques, the incorporation of different nanomaterials into epoxy-based solid polymer electrolytes, and an evaluation of their multifunctional properties. This comprehensive evaluation will cover both mechanical and electrical properties with a specific focus on their potential applications in batteries and structural supercapacitors.
摘要:
环氧基固体聚合物电解质的潜在应用由于其通用特性而不断扩大。这些特性包括机械刚性,非波动性,不易燃性,和电化学稳定性。然而,值得注意的是,与传统液体电解质相比,纯环氧基固体聚合物电解质固有地表现出较低的离子传输能力。在室温下达到高机械完整性和优异的离子电导率之间的平衡提出了重大挑战。鉴于这一挑战,这篇综述致力于阐明环氧基固体聚合物电解质的基本概念。它将探索各种准备技术,将不同的纳米材料掺入环氧基固体聚合物电解质中,并评估它们的多功能特性。这种综合评估将涵盖机械和电气性能,特别关注它们在电池和结构超级电容器中的潜在应用。
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