PDF(Pubmed)
Abstract：
Intermolecular metal-catalyzed C‒C couplings of unactivated primary alcohols or aldehydes to form ketones are catalogued. Reactions are classified on the basis of pronucleophile. Protocols involving premetalated reagents or reactants that incorporate directing groups are not covered. These methods represent an emerging alternative to classical multi-step protocols for ketone construction that exploit premetalated reagents, and/or steps devoted to redox manipulations and carboxylic acid derivatization.
摘要：
对未活化的伯醇或醛的分子间金属催化的C-C偶联形成酮进行了分类。反应根据原核亲核试剂进行分类。不包括涉及预金属化试剂或引入导向基团的反应物的方案。这些方法代表了一种新兴的替代方法，用于利用预金属化试剂的酮构建的经典多步骤方案，和/或专用于氧化还原操作和羧酸衍生化的步骤。
