关键词: Acylation Heterocyclic MgCl2 Synthesis

Mesh : Animals Biochemistry Chemistry, Organic Coloring Agents / chemistry Humans Magnesium Chloride / chemistry pharmacology Water Pollutants, Chemical / chemistry Water Purification

来  源:   DOI:10.1007/s11030-019-09947-2   PDF(Sci-hub)

Abstract:
MgCl2 has been reported to be a versatile reagent especially as a Lewis acid catalyst in a variety of organic transformations including the preparation of heterocyclic compounds, the protection of functional groups and condensation reaction. Also the use of MgCl2 in the preparation of metallic magnesium and the application of magnesium chloride in biochemistry such as anesthetic for cephalopods, the separation of serum high-density lipoprotein, effect of MgCl2 on rabbit bronchial smooth muscle, antimicrobial properties of magnesium chloride and effect of MgCl2 on the quality of life for patients with fibromyalgia have been reported. Therefore, in this article the use of MgCl2 in organic chemistry and biochemistry is reviewed. MgCl2 has been reported to be a versatile reagent especially as a Lewis acid catalyst in a variety of organic transformations including the preparation of heterocyclic compounds, the protection of functional groups and condensation reaction. Also the use of MgCl2 in the preparation of metallic magnesium and the application of magnesium chloride in biochemistry such as anesthetic for cephalopods, the separation of serum high-density lipoprotein, effect of MgCl2 on rabbit bronchial smooth muscle, antimicrobial properties of magnesium chloride and effect of MgCl2 on the quality of life for patients with fibromyalgia have been reported. Therefore, in this article the use of MgCl2 in organic chemistry and biochemistry is reviewed.
摘要:
据报道,MgCl2是一种通用试剂,特别是在各种有机转化中作为路易斯酸催化剂,包括制备杂环化合物,官能团的保护和缩合反应。此外,MgCl2在制备金属镁中的应用以及氯化镁在生物化学中的应用,例如头足类动物的麻醉剂,血清高密度脂蛋白的分离,MgCl2对兔支气管平滑肌的影响,氯化镁的抗菌性能和MgCl2对纤维肌痛患者生活质量的影响已有报道。因此,本文综述了MgCl2在有机化学和生物化学中的应用。据报道,MgCl2是一种通用试剂,特别是在各种有机转化中作为路易斯酸催化剂,包括制备杂环化合物,官能团的保护和缩合反应。此外,MgCl2在制备金属镁中的应用以及氯化镁在生物化学中的应用,例如头足类动物的麻醉剂,血清高密度脂蛋白的分离,MgCl2对兔支气管平滑肌的影响,氯化镁的抗菌性能和MgCl2对纤维肌痛患者生活质量的影响已有报道。因此,本文综述了MgCl2在有机化学和生物化学中的应用。
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