关键词: Caesalpinia minax Hance Diterpenoids Norcassane

Mesh : Biosynthetic Pathways Caesalpinia / chemistry Diterpenes / chemistry isolation & purification Magnetic Resonance Spectroscopy Molecular Structure Plant Extracts / chemistry Seeds / chemistry

来  源:   DOI:10.1016/j.fitote.2015.03.006   PDF(Sci-hub)

Abstract:
An unprecedented trinorcassane diterpenoid and a cassane furanoditerpenoid were isolated from the seeds of Caesalpinia minax. It is the first example of dicylic cassane-type trinorditerpenoid, which is different from reported 16- or 17-norcassane diterpenoids. The structure of the compounds was elucidated on the basis of 1D and 2D NMR analysis. Biosynthesis pathways are postulated, and this pathway was supported by semi-synthesis.
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