关键词: amination amines nitrenoids nitrogen synthetic methods

来  源:   DOI:10.1002/chem.201405779   PDF(Sci-hub)

Abstract:
Among the numerous approaches and reagents employed for electrophilic amination, nitrenoids have long stayed out of the limelight. Here, we systematically review the discovery, structural features and chemical reactivity of these promising reagents. We highlight advances in applying the chemistry of nitrenoids as well as outline current limitations and future directions.
摘要:
在用于亲电胺化的众多方法和试剂中,一氧化氮长期以来一直不在聚光灯下。这里,我们系统地回顾了这一发现,这些有前途的试剂的结构特征和化学反应性。我们重点介绍了应用类硝基化合物化学的进展,并概述了当前的局限性和未来的方向。
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